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HETEROCYCLIC
HETEROCYCLIC
COMPOUNDS
COMPOUNDS
DEFINITION OF HETEROCYCLIC COMPOUNDS:
Heterocyclic compounds are cyclic compounds which contains
one/more atoms of other elements along with carbon atoms.
DEFINITION OF HETEROATOM:
Hetero atoms are those which contains an atom other than
carbon such as nitrogen, sulphur, phosphorus etc.
CLASSIFICATION:
CLASSIFICATION:
Depending upon the size of heterocyclic ring, they are classified into
diferent types.
Five membered heterocyclic compounds:
NH S O O NH N
N N N N
N N
isooxazole H
pyrazole thiazole furan pyrrole tetrazole
Six membered heterocyclic compounds:
N
NH S
N
Pyridine piperidine thiazine
Fused heterocyclic compounds:
N
N
N
H
quinoline isoquinoline indole
Condensed ring systems:
H
N
N
benzimidazole
NOMENCLATURE
Systematic nomenclature system is used for naming 3-10 membered
monocyclic heterocyclics of various degree of the unstauration containing
one/more heteroatoms.
It specifies the following characters such as:
- the ring size
-the nature
-the type of heteroatom
- the position of heteroatom etc.
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