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Key questions:
What are isotopes?
What are the types of isotopes?
How do we measure isotopes?
How do we express measurements of isotopes?
What is isotope fractionation and how do we express it?
What is equilibrium isotope fractionation?
What is kinetic isotope fractionation?
What is Raleigh distillation?
What are some applications of stable isotopes?
Isotopes of Elements
Atomic Number = # Protons = defines which element and its chemistry
Atomic Weight = protons + neutrons = referred to as isotopes
Different elements have different numbers of neutrons and thus atomic
weights.
Example: Carbon can exist as 12C, 13C, 14C
How many protons and neutrons in each of the C isotopes?
12C = 6P, 6N
13C = 6P, 7N
14C = 6P, 8N
1 chemical, many isotopes!
Where do Isotopes come from?
In the beginning (Big Bang), light elements of H and He were
formed (and a little bit of Li)
Nuclear reactions (ie: fusion) in stars created the remaining
elements (and are still creating), some of which have since
decayed to more stable elements
There are 92 naturally occurring elements – some are stable,
some are not
Types of Isotopes
Isotopes can be categorized into 2 categories:
Stable isotopes – Isotopes that do not decay over the timescale of
earth history (4.5 billion years)
Radioactive isotopes – Isotopes that spontaneously convert into
other nuclei at a discernable rate
The chart of the nuclides (protons versus neutrons)
for elements 1 (Hydrogen) through 12 (Magnesium).
Valley of Stability
Most elements have more
than one stable isotope.
1:1 line b decay X
X
a decay
Number of neutrons tends
to be greater than the
number of protons
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