279x Filetype PPT File size 2.74 MB Source: www.snolab.ca
Drivers behind geo- and
cosmochemical analysis
Desire to analyze sub-
nanogram quantities of
implanted solar wind,
returned cometary
material, dust in Antarctic
ice, etc.
Analytic equipment: SIMS
Secondary ion mass spectrometer
Pros: Ideal for in situ analysis, quasi non-
destructive, high spatial resolution, high mass
resolution, for some elements ppt detection
limits
Cons: sample in ultra-high vacuum, requires
perfect surface for ppt analysis, matrix effects,
slow, and $
Analytic equipment: ICP-MS
Inductively coupled plasma mass spectrometer
Pros: ppq detection limits, can work in situ or
analyze digests, samples at atmospheric P,
matrix insensitive, fast, relatively inexpensive
Cons: destructive, requires more material than
SIMS, prone to blank contamination during
sample preparation, may require elemental pre-
concentration
Solution ICP-MS
Instrumental limits: ICP-MS
Sensitivity: 450,000 cps ppb-1
Detection limit: 1 cps
Consumed mass: 2 grams
Absolute mass of detected material: 4-5
femtograms (10-15g)
Dilution factor (solution/solid ratio): 1,000
Hence in 2 g of solution, only 2 mg of solid
translates to minimum detectable concentration
-1
of 4-5 nanograms g (ppt)
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